Typically, a larger enclosure will net lower bass, so you'd be better off at 2 ft^3. I wouldn't worry too much though, if you're fiberglassing, if youre enclosure is somewher between 1-2 ft^3, you should be fine.
Polyfill is just the filling inside our pillow, just go to Walmart and buy a bag of the filling for a couple bucks and you should be fine. You can also use fiberglass, but that's just itchier
